Pharmaceutical Organic Chemistry II Study Material

 Pharmaceutical Organic Chemistry II (Unit:- 1) Study Material

 

Benzene and its derivatives:

o   Analytical, synthetic and other evidences in the derivation of structure of benzene, Orbital picture, resonance in benzene, aromatic characters, Huckel’s rule

o   Reactions of benzene - nitration, sulphonation, halogenation- reactivity, Friedelcrafts alkylation- reactivity, limitations, Friedelcrafts acylation.

o   Substituents, effect of substituents on reactivity and orientation of mono substituted benzene compounds towards electrophilic substitution reaction

o   Structure and uses of DDT, Saccharin, BHC and Chloramine

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Pharmaceutical Organic Chemistry II (Unit:- 2) Study Material

Phenols*:

Acidity of phenols, effect of substituents on acidity, qualitative tests, Structure and uses of phenol, cresols, resorcinol, naphthols.

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Aromatic Amines*:

Basicity of amines, effect of substituents on basicity, and synthetic uses of aryl diazonium salts

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Aromatic Acids*:

Acidity, effect of substituents on acidity and important reactions of benzoic acid.

 

 

 

 

 

Pharmaceutical Organic Chemistry II (Unit:- 3) Study Material

 

 Fats and Oils:

·       Fatty acids – reactions.

·       Hydrolysis, Hydrogenation, Saponification and Rancidity of oils, Drying oils.

·       Analytical constants – Acid value, Saponification value, Ester value, Iodine value, Acetyl value, Reichert Meissl (RM) value – significance and principle involved in their determination.

 

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Pharmaceutical Organic Chemistry II (Unit:- 4) Study Material

 

Polynuclear hydrocarbons:

·       Synthesis, reactions

·       Structure and medicinal uses of Naphthalene, Phenanthrene, Anthracene, Diphenylmethane,         Triphenylmethane and their derivatives.

 

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Pharmaceutical Organic Chemistry II (Unit:- 5) Study Material

 

Cyclo alkanes*:

·       Stabilities – Baeyer’s strain theory, limitation of Baeyer’s strain theory, Coulson and Moffitt’s modification, Sachse Mohr’s theory (Theory of strainless rings), reactions of cyclopropane and cyclobutane only.

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